Electronic structure of solid nitromethane: Effects of high pressure and molecular vacancies

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Electronic structure of solid nitromethane: Effects of high pressure and molecular vacancies

The combined effect of pressure and molecular vacancies on the atomic structure and electronic properties of solid nitromethane, a prototypical energetic material, is studied at zero temperature. The self-consistent charge density-functional tight-binding method is applied in order to investigate changes induced in the band gap of this system by uniform and uniaxial strain of up to 70%, corresp...

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HIGH PRESSURE BEHAVIOR OF KCl: STRUCTURAL AND ELECTRONIC PROPERTIES

The high pressure behavior of the structural and electronic properties of KC1 is studied with use of the density functional pseudopotential method within local-density approximation. Atzero pressure, the rocksalt phase is found to be lower in energy than CsCl structure. However, we predict a phase transition into CsCI structure at a pressure of about 1.5 GPa. The calculated ground state pro...

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ژورنال

عنوان ژورنال: The Journal of Chemical Physics

سال: 2002

ISSN: 0021-9606,1089-7690

DOI: 10.1063/1.1466830